Belite-Based Low-Carbon Clinker Cements

Photo: Clinker used in the production of reactive belite-rich Portland cements (RBPC) suitable for the manufacture of low-heat, high-performance, high-strength concrete.

While Portland cement is expected to remain the most-used cement type
in concrete production, alternative cements are gaining importance.
In China over the last two decades,
Tongbo Sui, Sonoma Research Institute-China;
Hao Sui, Monash University-Australia; and
Bin Wang, Sinoma Research Institute-China
have seen this in the continued development of alternative clinkers—
such as belite-based low-carbon clinkers
with a belite content of more than 40%.

Alite is the most important constituent of normal Portland cement (PC) clinker, mostly accounts for 50% to 70% of PC clinker mineralogical composition, while belite is generally 15% to 30%. However, a study into the development of belite-based alternative clinkers has been ongoing for some time. The lower heat development and improved later-age strength of these clinkers was viewed as particularly beneficial in dam construction with mass concrete. The first successful use of belite-rich Portland cement (BPC) (ASTM C-150 Type IV, Low Heat Portland Cement) was applied in the USA between 1931 and 1936 for the construction of the Hoover Dam. However, BPC application was limited until the 1970s due to the construction industry’s concerns of very low early-age strength.

During the 1970s global energy crisis, research into BPC saw a revival in many countries due to its low energy demand. Yet, BPC was applied less on an industrial-scale until 1996 when China developed reactive belite-rich Portland cement (RBPC) (GB200-2003, Low Heat Portland Cement) as a type of low-energy, low-emission, high-performance cement with acceptable 3- to 7-day early strength, 28-day strength equivalent to PC and improved durability.

Since 2000 industrial manufacturing and field applications have held some hope of reversing the trend of clinkering more C3S with a finer cement particle size in the pursuit of higher early strength and a shorter turnaround time.

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